Bright phosphorescence of a trinuclear copper(I) complex: luminescence thermochromism, solvatochromism, and "concentration luminochromism".

نویسندگان

  • H V Rasika Dias
  • Himashinie V K Diyabalanage
  • Manal A Rawashdeh-Omary
  • Matthew A Franzman
  • Mohammad A Omary
چکیده

A photophysical study is reported for the trinuclear copper(I) complex {[3,5-(CF3)2Pz]Cu}3. The neutral compound exhibits multicolor bright phosphorescent emissions both in the solid state and in solution. The emission can be tuned to multiple visible colors by controlling the temperature, solvent, and {[3,5-(CF3)2Pz]Cu}3 concentration, giving rise to luminescence thermochromism, luminescence solvatochromism, and a new optical phenomenon called "concentration luminochromism", respectively.

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عنوان ژورنال:
  • Journal of the American Chemical Society

دوره 125 40  شماره 

صفحات  -

تاریخ انتشار 2003